What seedcorn said.
Limestone is 0-0-0. It has NO nitrogen or phosphorus or potassium; what it has is calcium (it is calcium carbonate).
If your soil is deficient in calcium, adding calcium is useful. However it is not going to do anything for a plant's N, P or K needs.
IME more cases of blossom-end rot (which is what people recommend calcium additions for, for tomatoes) are caused by uneven watering than by actual calcium deficiency as such, so personally in the absence of a soil test I would not go out of my way to add much if any calcium, what I'd devote my energy to is improving the soil's general tilth and fertility, preferably with reasonably-well-balanced compost. You can add additional fertilizer as the growing season progresses if your plants appear to be languishing.
JMHO, good luck, have fun,
Pat